URN: http://vtn.chdtu.edu.uaurn:2306:44553.2019.178444

DOI: https://doi.org/10.24025/2306-4412.3.2019.178444

GREEN SYNTHESIS OF SILVER NANOPARTICLES AND THEIR CATALYTIC APPLICATION FOR THE DEGRADATION OF ORGANIC POLLUTANTS

M. I. Skiba, О. А. Pivovarov, V. I. Vorobyova

Анотація


A simple and rapid method of green synthesis of silver nanoparticles (AgNPs) was developed using aqueous extract of grape pomas (GP) obtained from by plasma-chemical extraction technique, and their catalitic potential was investigated. With this aim, the plasma-chemical obteained aqueous solutions of grape pomace and AgNO3 (0.25-6.0 mM) were mixed (1:1 v/v), and heated for 10 mim. The synthesized GP-AgNPs were characterized by UV-visible spectroscopy, AFM, DSL analyses. The synthesized AgNPs showed an intense surface plasmon resonance band at 405-420 nm. The AgNPs were in highly uniform shape (everage size 20 nm). The role of pH in the green synthesis of silver nanoparticles (AgNPs) is investigated. The presence of silver nanoparticles with sun light was proven very effective for degradation of organic dyes. The reaction kinetics was found to be pseudo first order with respect to the dye concentration. The outcomes of the current study confirmed that the synthesized AgNPs had an awesome guarantee for application in catalysis and wastewater treatmen.

Ключові слова


silver nanoparticles; plasma discharge; aqueous extract; frute waster; methilen blu.

Повний текст:

PDF (English)

Посилання


W. Zhang, X. Xiao, T. An, Z. Song, J. Fu, G. Sheng, and M. Cui, "Kinetics, degradation pathway and reaction mechanism of advanced oxidation of 4-nitrophenol in water by a UV/H2O2 process," J. Chem. Technol. Biotechnol., vol. 78, pp. 788-794, 2003.

R. Dai, J. Chen, J. Lin, S. Xiao, S. Chen, and Y. Deng, "Reduction of nitro phenols using nitroreductase from E. coli in the presence of NADH," J. Hazard. Mater., vol. 170, pp. 141-143, 2009.

M. Nasrollahzadeh, E. Mehdipour, and M. Maryami, "Efficient catalytic reduction of nitroarenes and organic dyes in water by synthesized Ag/diatomite nanocomposite using Alocasia macrorrhiza leaf extract", J. Mater. Sci. Mater. Electron., vol. 29, pp. 17054-17066, 2018.

V. Vidhu, and D. Philip, "Catalytic degradation of organic dyes usingbiosynthesized silver nano-particles", Micron, vol. 56, pp. 54-62, 2014.

B. Manu, and S. Chaudhari, "Anaerobic decolorisation of simulated textile wastewater containing azo dyes", Bioresour. Technol., vol. 82, pp. 225-231, 2002.

K. T. Chung, and C. E. Cerniglia, "Mutagenicity of azo dyes: structureactivity relationships", Mutat. Res., vol. 277, pp. 201-220, 1992.

M. Boxall, S. C. Monteiro, A. B. A. Boxall, "Factors affecting the degradation of pharmaceuticals in agricultural soils", Environmental Toxicology and Chemistry, vol. 28 (12), pp. 2546-2554, 2009.

D. Tiwari, J. Behari, and P. Sen, "Application of nanoparticles in waste water treatment". World Appl. Sci. J., vol. 3, pp. 417-433, 2008.

S. Das, J. Chakraborty, S. Chatterjee, and H. Kumar, "Prospects of biosynthesized nanomaterials for remediation of organic and inorganic environmental contaminants", Environmental Science: Nano., vol. 5, pp. 2784-2808, 2018.

S. Das, B. Sen, and N. Debnath, "Recent trends in nanomaterials applications in environmental monitoring and remediation", Environ. Sci. Pollut. Res., vol. 22, pp. 18333-18344, 2015.[11] B. Nowack, H. F. Krug, and M. Height, "120 years of nanosilver history: implications for policy makers", Environmental Science and Technology, vol. 45, no. 4, pp. 1177-1183, 2011.

T. Quang Huy, N. van Quy, and L. Anh-Tuan, "Silver nanoparticles: synthesis, properties, toxicology, applications and perspectives", Advances in Natural Sciences: Nanoscience and Nanotechnology, vol. 4, no. 3, p. 033001, 2013.

Y. A. Krutyakov, A. A. Kudrinskiy, A. Y. Olenin, and G. V. Lisichkin, "Synthesis and properties of silver nanoparticles: advances and prospects", Russian Chemical Reviews, vol. 77, no. 3, pp. 233-257, 2008.

Isiaka A. Adelere, and Agbaje Lateef, "A novel approach to the green synthesis of metallic nanoparticles: The use of agro-wastes, enzymes, and pigments", Nanotechnology Reviews, vol. 5, no. 6, pp. 567-587, 2016.

M. I. Skiba, A. A. Pivovarov, A. K. Makaro-va, and V, I. Vorobyova, "Plasma-chemical synthesis of silver nanoparticles in the presence of citrate", CJM.ASM.MD., vol. 13, no. 1, pp. 7-14, 2018.

M. Skiba, A. Pivovarov, V. Vorobyova, T. Derkach, and I. Kurmakova, "Plasma-chemical formation of silver nanoparticles: The silver ions concentration effect on the particle size and their antimicrobial properties", Journal of Chemical Technology and Metallurgy, vol. 54, no. 2, pp. 311-318, 2019.


Пристатейна бібліографія ГОСТ


[1] W. Zhang, X. Xiao, T. An, Z. Song, J. Fu, G. Sheng, and M. Cui, "Kinetics, degradation pathway and reaction mechanism of advanced oxidation of 4-nitrophenol in water by a UV/H2O2 process," J. Chem. Technol. Biotechnol., vol. 78, pp. 788-794, 2003.

[2] R. Dai, J. Chen, J. Lin, S. Xiao, S. Chen, and Y. Deng, "Reduction of nitro phenols using nitroreductase from E. coli in the presence of NADH," J. Hazard. Mater., vol. 170, pp. 141-143, 2009.

[3] M. Nasrollahzadeh, E. Mehdipour, and M. Maryami, "Efficient catalytic reduction of nitroarenes and organic dyes in water by synthesized Ag/diatomite nanocomposite using Alocasia macrorrhiza leaf extract", J. Mater. Sci. Mater. Electron., vol. 29, pp. 17054-17066, 2018.
[4] V. Vidhu, and D. Philip, "Catalytic degradation of organic dyes usingbiosynthesized silver nano-particles", Micron, vol. 56, pp. 54-62, 2014.

[5] B. Manu, and S. Chaudhari, "Anaerobic decolorisation of simulated textile wastewater containing azo dyes", Bioresour. Technol., vol. 82, pp. 225-231, 2002.

[6] K. T. Chung, and C. E. Cerniglia, "Mutagenicity of azo dyes: structureactivity relationships", Mutat. Res., vol. 277, pp. 201-220, 1992.

[7] M. Boxall, S. C. Monteiro, A. B. A. Boxall, "Factors affecting the degradation of pharmaceuticals in agricultural soils", Environmental Toxicology and Chemistry, vol. 28 (12), pp. 2546-2554, 2009.

[8] D. Tiwari, J. Behari, and P. Sen, "Application of nanoparticles in waste water treatment". World Appl. Sci. J., vol. 3, pp. 417-433, 2008.

[9] S. Das, J. Chakraborty, S. Chatterjee, and H. Kumar, "Prospects of biosynthesized nanomaterials for remediation of organic and inorganic environmental contaminants", Environmental Science: Nano., vol. 5, pp. 2784-2808, 2018.

[10] S. Das, B. Sen, and N. Debnath, "Recent trends in nanomaterials applications in environmental monitoring and remediation", Environ. Sci. Pollut. Res., vol. 22, pp. 18333-18344, 2015.[11] B. Nowack, H. F. Krug, and M. Height, "120 years of nanosilver history: implications for policy makers", Environmental Science and Technology, vol. 45, no. 4, pp. 1177-1183, 2011.

[12] T. Quang Huy, N. van Quy, and L. Anh-Tuan, "Silver nanoparticles: synthesis, properties, toxicology, applications and perspectives", Advances in Natural Sciences: Nanoscience and Nanotechnology, vol. 4, no. 3, p. 033001, 2013.

[13] Y. A. Krutyakov, A. A. Kudrinskiy, A. Y. Olenin, and G. V. Lisichkin, "Synthesis and properties of silver nanoparticles: advances and prospects", Russian Chemical Reviews, vol. 77, no. 3, pp. 233-257, 2008.

[14] Isiaka A. Adelere, and Agbaje Lateef, "A novel approach to the green synthesis of metallic nanoparticles: The use of agro-wastes, enzymes, and pigments", Nanotechnology Reviews, vol. 5, no. 6, pp. 567-587, 2016.

[15] M. I. Skiba, A. A. Pivovarov, A. K. Makaro-va, and V, I. Vorobyova, "Plasma-chemical synthesis of silver nanoparticles in the presence of citrate", CJM.ASM.MD., vol. 13, no. 1, pp. 7-14, 2018.

[16] M. Skiba, A. Pivovarov, V. Vorobyova, T. Derkach, and I. Kurmakova, "Plasma-chemical formation of silver nanoparticles: The silver ions concentration effect on the particle size and their antimicrobial properties", Journal of Chemical Technology and Metallurgy, vol. 54, no. 2, pp. 311-318, 2019.





Copyright (c) 2019 Маргарита Івановна Скиба, Александр Андреійович Півоваров, Вікторія Іванівна Воробйова